3,5-Heptanedione → 2,6-Dimethyl-3,5-heptandiol

反応式

CCC(=O)CC(=O)CC.[CH3:10][CH:11]([C:13](=[O:20])[CH2:14][C:15](=[O:19])[CH:16]([CH3:18])[CH3:17])[CH3:12]>>[CH3:18][CH:16]([CH:15]([OH:19])[CH2:14][CH:13]([OH:20])[CH:11]([CH3:12])[CH3:10])[CH3:17]

参加物

反応物 2

HCID 819233,5-Heptanedione

HCID 875973,5-Heptanedione, 2,6-dimethyl-

生成物 1

HCID 136231122,6-Dimethyl-3,5-heptandiol収率 90%

実験手順

Synthesis procedure was similar to that described in synthetic example 19(1), except that 3,5-heptandione was replaced by 2,6-dimethyl-3,5-heptandione, and finally the product was purified by distilling under reduced pressure. 2,6-dimethyl-3,5-heptandiol as a colorless liquid was obtained with a yield of 90%.

後処理

customSynthesis procedure
customfinally the product was purified
distillationby distilling under reduced pressure

出典と根拠

ORDレコード: ord-04ac086d882341f888b8d3d82bf35919
出典データセット: uspto-grants-2008_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07388061B2

反応ノート

読み込み中…

参加物