Potassium hydride → Potassium (2-trimethylsiloxy-ethyl)-cyclopentadienide

HRID 1348536ノート

反応式

HRID 1348536 の反応式
[H-].[K+:2].[CH3:3][Si:4]([CH3:14])([CH3:13])[O:5][CH2:6][CH2:7][C:8]1[CH2:12][CH:11]=[CH:10][CH:9]=1>O1CCCC1>[CH3:13][Si:4]([CH3:3])([CH3:14])[O:5][CH2:6][CH2:7][C-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[K+:2]

参加物

4

反応物 2

HCID 82127Potassium hydrideHCID 23303830(2-Trimethylsiloxy-ethyl)-cyclopentadiene

生成物 1

HCID 86199137Potassium (2-trimethylsiloxy-ethyl)-cyclopentadienide収率 81%

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒2 回

実験手順

To a suspension of 0.5 g (12.4 mmol) of potassium hydride in tetrahydrofurane, 2.25 g (12.4 mmol) of (2-trimethylsiloxy-ethyl)-cyclopentadiene in tetrahydrofurane is added. The reaction is maintained under stirring for 2 hours and then the volatile compounds are eliminated, leaving an oily solid which is washed with hexane in order to obtain a brown solid. (2.2 g Yield: 81%)

後処理

  1. additionis added
  2. temperatureThe reaction is maintained
  3. customleaving an oily solid which
  4. washis washed with hexane in order
  5. customto obtain a brown solid

出典と根拠

ORDレコード
ord-14c3487f2344425e8598f66d19662062
出典データセット
uspto-grants-2007_05
特許番号
US07211538B2

反応ノート

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