Acetone → HCID 23077311、化合物
反応式
[CH3:1][C:2](C)=O.[F:5][C:6]1[C:15]2[C:10](=[CH:11][CH:12]=[C:13]([F:17])[C:14]=2[F:16])[CH:9]=[CH:8][C:7]=1[OH:18].C(=O)([O-])[O-].[K+].[K+].C(I)C>C1(C)C=CC=CC=1>[CH2:1]([O:18][C:7]1[CH:8]=[CH:9][C:10]2[C:15](=[C:14]([F:16])[C:13]([F:17])=[CH:12][CH:11]=2)[C:6]=1[F:5])[CH3:2]参加物
6
実験手順
An acetone (80 ml) solution of 1,7,8-trifluoro-2-naphthol (15 g), potassium carbonate (16 g), and ethyl iodide (26 g) was stirred for 10 hours at room temperature. Toluene (200 ml) was added in this reaction solution. The organic layer was removed, and the aqueous layer was extracted with toluene. The organic layers were combined, washed with brine, and concentrated. The residue was evaporated under reduced pressure, and 2-ethoxy-1,7,8-trifluoronaphthalene was obtained.
後処理
- customThe organic layer was removed
- extractionthe aqueous layer was extracted with toluene
- washwashed with brine
- concentrationconcentrated
- customThe residue was evaporated under reduced pressure
出典と根拠
- ORDレコード
- ord-c21c67302d004c128768a2f166002c3a
- 出典データセット
- uspto-grants-2007_05
- 特許番号
- US07214835B2
反応ノート
読み込み中…