Triphenylphosphine → HCID 69519174、化合物
反応式
C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[N:20]([CH2:23][C:24]1[CH2:29][N:28]([NH:30][C:31]([O:33][C:34]([CH3:37])([CH3:36])[CH3:35])=[O:32])[CH2:27][CH2:26][CH:25]=1)=[N+]=[N-]>C1COCC1.O>[NH2:20][CH2:23][C:24]1[CH2:29][N:28]([NH:30][C:31]([O:33][C:34]([CH3:37])([CH3:36])[CH3:35])=[O:32])[CH2:27][CH2:26][CH:25]=1参加物
5
実験手順
Triphenylphosphine on polystyrene (5.24 g) was added to a solution of tert-butyl 5-azidomethyl-3,6-dihydro-2H-pyridine-1-carbamate (1 g, 4.2 mmol) in THF (25 ml) and water (0.250 ml). The reaction mixture was shaken at room temperature for 36 hours. The polymer was filtered off and then washed with THF. The filtrate was concentrated.
後処理
- filtrationThe polymer was filtered off
- washwashed with THF
- concentrationThe filtrate was concentrated
出典と根拠
- ORDレコード
- ord-915055fef30541c99e0f6165803acee0
- 出典データセット
- uspto-grants-2007_05
- 特許番号
- US07223776B2
反応ノート
読み込み中…