2-(Dibutylamino)ethanol → HCID 86588641、化合物

HRID 1355304

反応式

HRID 1355304 の反応式
[B:1]([OH:4])([OH:3])[OH:2].[CH2:5]([O:9][CH2:10][CH2:11][O:12][CH2:13][CH2:14][O:15][CH2:16][CH2:17]O)[CH2:6][CH2:7][CH3:8].[CH2:19]([N:23]([CH2:27][CH2:28][CH2:29][CH3:30])[CH2:24][CH2:25][OH:26])[CH2:20][CH2:21][CH3:22]>C1(C)C=CC=CC=1>[CH2:19]([N:23]([CH2:27][CH2:28][CH2:29][CH3:30])[CH2:24][CH2:25][OH:26])[CH2:20][CH2:21][CH3:22].[B:1]([O-:4])([O-:3])[O:2][CH2:17][CH2:16][O:15][CH2:14][CH2:13][O:12][CH2:11][CH2:10][O:9][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

5

反応物 3

HCID 76212-(Dibutylamino)ethanolHCID 7628Boric AcidHCID 8923Triethylene glycol monobutyl ether

生成物 1

HCID 86588641HCID 86588641、化合物収率 128.2%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

N,N-dibutylethanolamine/triethylene glycol monobutyl ether borate was prepared as follows. Boric acid (10.3 grams), triethylene glycol monobutyl ether (Fluka, 64.1 grams), and N,N-dibutylethanolamine (28.9 grams) were added to a 250 milliliter flask. One hundred fifty milliliters of toluene was then added. The reaction was allowed to proceed overnight at 110° C., and the byproduct water (˜9 grams) was continuously removed from the reaction by azeotropic distillation. The final solution was evaporated to remove toluene under vacuum, and a brownish liquid product (˜90 grams) of N,N-dibutylethanolamine/triethylene glycol monobutyl ether borate was obtained.

後処理

  1. customN,N-dibutylethanolamine/triethylene glycol monobutyl ether borate was prepared
  2. customthe byproduct water (˜9 grams) was continuously removed from the reaction by azeotropic distillation
  3. customThe final solution was evaporated
  4. customto remove toluene under vacuum

出典と根拠

ORDレコード
ord-ca8263fea736495ba37e1f449f03e23f
出典データセット
uspto-grants-2003_07
特許番号
US06585816B1

関連ノート

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