Acrylonitrile → 4,4-Diacetylheptanedinitrile
反応式
[OH-].[K+].[CH3:3][C:4](=[O:9])[CH2:5][C:6](=[O:8])[CH3:7].[C:10](#[N:13])[CH:11]=[CH2:12]>CO>[C:6]([C:5]([C:4](=[O:9])[CH3:3])([CH2:12][CH2:11][C:10]#[N:13])[CH2:12][CH2:11][C:10]#[N:13])(=[O:8])[CH3:7]参加物
5
実験手順
After addition of 0.25 g of KOH, dissolved in 2.5 ml of methanol, to 15.0 g of 2,4-pentandione, 35.0 g of acrylonitrile was added dropwise with the reaction temperature not exceeding 40° C. The product which was precipitated during the process was filtered off, washed with a small amount of acetone, and dried. Melting point: 185–186° C. Purity>98%. The product was colorless.
後処理
- additionwas added dropwise with the reaction temperature not
- customexceeding 40° C
- customThe product which was precipitated during the process
- filtrationwas filtered off
- washwashed with a small amount of acetone
- customdried
出典と根拠
- ORDレコード
- ord-758eda3c20a4438ca313d26eead9b2f5
- 出典データセット
- uspto-grants-2007_01
- 特許番号
- US07166648B2
反応ノート
読み込み中…