Potassium Hydroxide → 3,3-Dimethyl-1-butene

反応式

[OH-:1].[K+].[OH-].[Na+].[CH2:5](Cl)[CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8]>>[CH2:5]=[CH:6][C:7]([CH3:10])([CH3:9])[CH3:8].[CH2:5]([OH:1])[CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8].[CH2:5]([O:1][CH2:5][CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8])[CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8]

参加物

反応物 3

HCID 14797Potassium Hydroxide2 回

HCID 14798Sodium Hydroxide

HCID 761111-Chloro-3,3-dimethylbutane

生成物 3

HCID 112103,3-Dimethyl-1-butene

HCID 122333,3-Dimethyl-1-butanol

HCID 226621881,1'-Oxybis(3,3-dimethylbutane)

実験手順

The procedure of Example 1 is followed; instead of using potassium hydroxide, 1 mole of potassium hydroxide and 1 mole of sodium hydroxide is utilized, as well as 2 moles of neohexyl chloride. A conversion of about 50% is attained in this procedure. The yields of neohexene, neohexanol, and dineohexyl ether, based on converted neohexyl chloride, are 70.0 mol-%, 6.1 mol-%, and 7.1 mol-%, respectively.