Lithium Hydroxide → 4-[[[5 (2-Propylphenoxy)pentyl]thio]methyl]-1,3-oxathiolane-2,2-dipropanoic acid
反応式
[CH2:1]([C:4]1[CH:36]=[CH:35][CH:34]=[CH:33][C:5]=1[O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][S:12][CH2:13][CH:14]1[CH2:18][O:17][C:16]([CH2:26][CH2:27][C:28]([O:30]CC)=[O:29])([CH2:19][CH2:20][C:21]([O:23]CC)=[O:22])[S:15]1)[CH2:2][CH3:3].[OH-].[Li+]>>[CH2:1]([C:4]1[CH:36]=[CH:35][CH:34]=[CH:33][C:5]=1[O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][S:12][CH2:13][CH:14]1[CH2:18][O:17][C:16]([CH2:19][CH2:20][C:21]([OH:23])=[O:22])([CH2:26][CH2:27][C:28]([OH:30])=[O:29])[S:15]1)[CH2:2][CH3:3]参加物
3
実験手順
The title compound was prepared according to the procedure of Example 3 using the ester produced in Example 8 (0.80 g, 0.0015 mol) and aqueous lithium hydroxide solution (2 M, 3.0 ml). The product, 0.78 g (89%), was obtained as an oil.
後処理
- customThe product, 0.78 g (89%), was obtained as an oil
出典と根拠
- ORDレコード
- ord-223084a2703a465287898caa9a2d1ace
- 出典データセット
- uspto-grants-1989_02
- 特許番号
- US04808729
反応ノート
読み込み中…