Ammonia → HCID 20297955、化合物

HRID 1389037ノート

反応式

HRID 1389037 の反応式
[CH2:1]([N:3]([CH2:14][CH3:15])[C:4]1[CH:5]=[C:6]([CH:11]=[CH:12][CH:13]=1)[CH2:7][CH2:8][C:9]#N)[CH3:2].[OH-:16].[Na+].N.[OH2:19]>>[CH2:1]([N:3]([CH2:14][CH3:15])[C:4]1[CH:5]=[C:6]([CH:11]=[CH:12][CH:13]=1)[CH2:7][CH2:8][C:9]([OH:19])=[O:16])[CH3:2]

参加物

5

反応物 4

HCID 222Ammonia2 回HCID 962WaterHCID 14798Sodium HydroxideHCID 202979473-[3-(Diethylamino)phenyl]propanenitrile

生成物 1

HCID 20297955HCID 20297955、化合物

実験手順

A mixture of 60.6 parts of 3-diethylamino-hydrocinnamonitrile, 250 parts by volume of methylated spirits of denatured alcohol, 100 parts of water and 60 parts by volume of a 35° Be solution of sodium hydroxide was heated under reflux until the evolution of ammonia ceased. After the evolution of ammonia had stopped, the mixture was cooled and then neutralized by addition of 19° Be hydrochloric acid. After filtering and drying, 3-diethylamino-hydrocinnamic acid was obtained of the formula:

後処理

  1. temperaturewas heated
  2. temperaturethe mixture was cooled
  3. filtrationAfter filtering
  4. customdrying

出典と根拠

ORDレコード
ord-5d1d1314b5084b60b98e18400c3fa9de
出典データセット
uspto-grants-1981_01
特許番号
US04243606

反応ノート

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