Triphenylphosphine → (3,5-Dimethoxybenzyl)triphenylphosphonium bromide

HRID 1389187

反応式

HRID 1389187 の反応式
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[C:9]([O:11][CH3:12])[CH:10]=1)[CH2:6][Br:7].[C:13]1([P:19]([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>C(#N)C>[Br-:7].[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[C:9]([O:11][CH3:12])[CH:10]=1)[CH2:6][P+:19]([C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)([C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1)[C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1

参加物

4

反応物 2

HCID 11776TriphenylphosphineHCID 12744903,5-Dimethoxybenzyl Bromide

生成物 1

HCID 10962038(3,5-Dimethoxybenzyl)triphenylphosphonium bromide

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

The 3,5-dimethoxybenzyl triphenylphosphonium bromide is prepared by refluxing a mixture of 3,5-dimethoxybenzyl bromide (12 g.) and triphenylphosphine (14.2 g.) in acetonitrile (200 ml.) for one hour. The reaction mixture is then cooled and the crystalline product recovered by filtration, washed with ether and dried (20 g.); m.p. 269°-270° C.

後処理

  1. temperatureby refluxing
  2. temperatureThe reaction mixture is then cooled
  3. filtrationthe crystalline product recovered by filtration
  4. washwashed with ether
  5. customdried (20 g.)

出典と根拠

ORDレコード
ord-38dd8724eeed44b5b7e0b0172da1adff
出典データセット
uspto-grants-1981_01
特許番号
US04243674

関連ノート

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