Tris(2-cyanoethyl)phosphine → HCID 20520070、化合物

HRID 1390175ノート

反応式

HRID 1390175 の反応式
[C:1]([CH2:3][CH2:4][P:5]([CH2:10][CH2:11][C:12]#[N:13])[CH2:6][CH2:7][C:8]#[N:9])#[N:2].[I:14][CH2:15][CH2:16][O:17][CH3:18]>C(#N)C>[I-:14].[C:1]([CH2:3][CH2:4][P+:5]([CH2:10][CH2:11][C:12]#[N:13])([CH2:6][CH2:7][C:8]#[N:9])[CH2:15][CH2:16][O:17][CH3:18])#[N:2]

参加物

4

反応物 2

HCID 77639Tris(2-cyanoethyl)phosphineHCID 791361-Iodo-2-methoxyethane

生成物 1

HCID 20520070HCID 20520070、化合物

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

135.2 g (0.7 mole) of tris-(2-cyanoethyl)-phosphine are dissolved, under nitrogen, in 500 ml of boiling acetonitrile and then 130.2 g (0.7 mole) of 1-iodo-2-methoxyethane are added. The mixture is refluxed for 12 hours. After rapid filtration of the hot solution and cooling, the reaction product crystallises out and is collected by suction filtration and dried in vacuo at 60° C.

後処理

  1. temperatureThe mixture is refluxed for 12 hours
  2. filtrationAfter rapid filtration of the hot solution
  3. temperaturecooling
  4. customthe reaction product crystallises out
  5. filtrationis collected by suction filtration
  6. customdried in vacuo at 60° C.

出典と根拠

ORDレコード
ord-40dd3f7af60e4ac0ae969581fe228a06
出典データセット
uspto-grants-1979_02
特許番号
US04138256

反応ノート

読み込み中…