化工社化工社 化学情報印刷レポート · 研究参考用
Sodium hydride → Sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium hydride | HCID 24758 | — |
| 反応物 | 2,6-Di-tert-butyl-4-(chloromethyl)phenol | HCID 12378601 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide | HCID 23699397 | — |
反応手順
To a stirred suspension of sodium hydride (2 g.) in dry dimethyl formamide (20 ml.) was added dropwise a solution of 4-chloromethyl-2, 6-di-tert-butylphenol (10 g.) in dimethyl formamide (40 ml.) at 25°-30° C. The mixture was stirred for 30 minutes, during which gas evolution ceased, so as to produce a solution of sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04138389 |
| 出典データセット | uspto-grants-1979_02 |
| ORD ID | ord-ed335a9a33ba478a905286c3c5f80dc1 |
| 出典メモ | uspto-grants-1979_02 |