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Sodium borohydride → 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium borohydride | HCID 4311764 | — |
| 反応物 | 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanone | HCID 21332846 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanol | HCID 21332842 | — |
反応手順
The ketone, 1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentanone (2 grams) was dissolved in 100 ml. of ethanol and stirred with 2 grams of sodium borohydride overnight. The solvent was removed in vacuo and the residue partitioned between ethyl ether and water. The organic layer was dried over sodium sulfate. After filtration, and removal of solvent a colorless oil was obtained that crystallized on standing, m.p. 55° C.-56° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04139559 |
| 出典データセット | uspto-grants-1979_02 |
| ORD ID | ord-8e660559ec5a4d1a89cdbf6e555f403d |
| 出典メモ | uspto-grants-1979_02 |