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HRID1390551

反应详情

EQUATION

反应方程式

HRID 1390551 的结构方程式

REACTANTS

反应物

2
结构：[BH4-].[Na+]
HCID4311764

Sodium borohydride (Na(BH4))

H4BNa

结构：CC1(C)C2CCC(C2)C1CCC(=O)CCC1C2CCC(C2)C1(C)C
HCID21332846

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)C2CCC(C2)C1CCC(O)CCC1C2CCC(C2)C1(C)C
HCID21332842

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

The ketone, 1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentanone (2 grams) was dissolved in 100 ml. of ethanol and stirred with 2 grams of sodium borohydride overnight. The solvent was removed in vacuo and the residue partitioned between ethyl ether and water. The organic layer was dried over sodium sulfate. After filtration, and removal of solvent a colorless oil was obtained that crystallized on standing, m.p. 55° C.-56° C.

WORKUP

后处理

  1. customThe solvent was removed in vacuo
  2. customthe residue partitioned between ethyl ether and water
  3. dry with materialThe organic layer was dried over sodium sulfate
  4. filtrationAfter filtration, and removal of solvent a colorless oil
  5. customwas obtained
  6. customthat crystallized