Lithium bis((trifluoromethyl)sulfonyl)azanide → 3-methyl-4-propyl-1-(pyridin-4-yl)-1H-1,2,3-triazol-3-ium bis((trifluoromethyl)sulfonyl)amide
反応式
[I-].[CH3:2][N+:3]1[C:7]([CH2:8][CH2:9][CH3:10])=[CH:6][N:5]([C:11]2[CH:16]=[CH:15][N:14]=[CH:13][CH:12]=2)[N:4]=1.[F:17][C:18]([F:31])([F:30])[S:19]([N-:22][S:23]([C:26]([F:29])([F:28])[F:27])(=[O:25])=[O:24])(=[O:21])=[O:20].[Li+]>C(#N)C>[F:29][C:26]([F:27])([F:28])[S:23]([N-:22][S:19]([C:18]([F:17])([F:30])[F:31])(=[O:20])=[O:21])(=[O:24])=[O:25].[CH3:2][N+:3]1[C:7]([CH2:8][CH2:9][CH3:10])=[CH:6][N:5]([C:11]2[CH:12]=[CH:13][N:14]=[CH:15][CH:16]=2)[N:4]=1参加物
4
実験手順
3-methyl-4-propyl-1-(pyridin-4-yl)-1H-1,2,3-triazol-3-ium iodide and lithium bis((trifluoromethyl)sulfonyl)amide were mixed in acetonitrile and stirred overnight. The acetonitrile was removed under vacuum and water and DCM added. The organic layer was washed three times with water and brine and dried in vacuum at 110° C. for 48 hours, yielding 3-methyl-4-propyl-1-(pyridin-4-yl)-1H-1,2,3-triazol-3-ium bis((trifluoromethyl)sulfonyl)amide.