Sodium Azide → 1-(2-Azidoethoxy)-2-(2-methoxyethoxy)ethane
反応式
[N-:1]=[N+:2]=[N-:3].[Na+].CS(O[CH2:10][CH2:11][O:12][CH2:13][CH2:14][O:15][CH2:16][CH2:17][O:18][CH3:19])(=O)=O>>[N:1]([CH2:10][CH2:11][O:12][CH2:13][CH2:14][O:15][CH2:16][CH2:17][O:18][CH3:19])=[N+:2]=[N-:3]参加物
3
反応条件
- 温度
- 60 °C
実験手順
Sodium azide (5.37 g, 83 mmol) and 2-(2-(2-methoxyethoxy)ethoxy)ethyl methanesulfonate (20 g, 83 mmol) were added without solvent, the temperature was raised to 60° C. and the mixture stirred for 48 hours. The salts were filtered and ethyl acetate added to precipitate the dissolved salts and filtered again, producing 1-azido-2-(2-(2-methoxyethoxy)ethoxy)ethane.
後処理
- filtrationThe salts were filtered
- additionethyl acetate added
- customto precipitate the dissolved salts
- filtrationfiltered again
出典と根拠
- ORDレコード
- ord-7dea1f94450c4aa0897b2f08013d7cef
- 出典データセット
- uspto-grants-2014_12
- 特許番号
- US08907105B1
反応ノート
読み込み中…