Tributylstannane → [4-(Difluoromethyl)-1-tributylstannyloct-1-en-4-yl]oxy-trimethylsilane

反応式

[CH2:17]([CH2:18][CH2:19][CH3:20])[SnH:21]([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:26][CH2:27][CH2:28][CH3:29].[F:1][CH:2]([C:3]([CH2:4][C:5]#[CH:6])([CH2:7][CH2:8][CH2:9][CH3:10])[O:11][Si:12]([CH3:13])([CH3:14])[CH3:15])[F:16].[N:30]#[C:31][C:32]([N:33]=[N:34][C:35]([C:36]#[N:37])([CH3:38])[CH3:39])([CH3:40])[CH3:41]>>[F:1][CH:2]([C:3]([CH2:4][CH:5]=[CH:6][Sn:21]([CH2:17][CH2:18][CH2:19][CH3:20])([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:26][CH2:27][CH2:28][CH3:29])([CH2:7][CH2:8][CH2:9][CH3:10])[O:11][Si:12]([CH3:13])([CH3:14])[CH3:15])[F:16]

参加物

反応物 3

HCID 5948Tributylstannane

HCID 6547Azobisisobutyronitrile

HCID 217647864-Difluoromethyl-4-trimethylsiloxy-1-octyne

生成物 1

HCID 73807161[4-(Difluoromethyl)-1-tributylstannyloct-1-en-4-yl]oxy-trimethylsilane

出典と根拠

ORDレコード: ord-ec73016662234015b1115ccfb24630f8
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…