HCID 12418397、化合物 → 1-Cyclohexyl-2,2,2-trichloroethanol

HRID 1413227ノート

反応式

HRID 1413227 の反応式
[CH:1]1([CH:7]([OH:12])[C:8]([Cl:11])([Cl:10])[Cl:9])[CH2:6][CH2:5][CH2:4][CH:3]=[CH:2]1.[H][H]>O=[Pt]=O.CO>[CH:1]1([CH:7]([OH:12])[C:8]([Cl:10])([Cl:11])[Cl:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1

参加物

5

反応物 2

HCID 12418397HCID 12418397、化合物HCID 178418361HCID 178418361、化合物2 回

生成物 1

HCID 105375101-Cyclohexyl-2,2,2-trichloroethanol

試薬・触媒・溶媒 2

HCID 345198Adams' catalyst触媒HCID 887Methanol溶媒

実験手順

Adam's catalyst (0.2 g) was added to a solution of 1-(2-cyclohexen-1-yl)-2,2,2-trichloroethanol (23 g) in methanol (220 ml) and this mixture was stirred under a slight positive pressure of hydrogen. Uptake of hydrogen was complete after 400 minutes and the solution was then filtered. The filtrate was evaporated to give 1-cyclohexyl-2,2,2-trichloroethanol of 90% purity as judged by G.L.C. An attempt to purify this material by distillation through a spinning band column gave material of only 85% purity due, presumably, to decomposition brought about by prolonged heating. This material was used without further treatment.

後処理

  1. filtrationthe solution was then filtered
  2. customThe filtrate was evaporated

出典と根拠

ORDレコード
ord-e23030b513fb41d9bc317093a146a7d5
出典データセット
uspto-grants-1981_02
特許番号
US04249015

反応ノート

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