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llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.8.0
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Hydrochloric Acid → Perylene

HRID 1413330
ノート
印刷プレビュー

反応式

HRID 1413330 の反応式
C(O)(=O)CCCCCCCCCCCCCCCCC.[C:21]1(C(O)=O)[C:38]2=[C:39]3[C:28]([C:29]4[C:40]5[C:33](=[CH:34][CH:35]=[CH:36][C:37]2=5)[CH:32]=[CH:31][CH:30]=4)=[CH:27][CH:26]=[C:25](C(O)=O)[C:24]3=[C:23](C(O)=O)[C:22]=1C(O)=O.C(O)(=O)CCCCCCCCCCCCCCCCC.C(N)CCCCCCCCCCCCCCCCC.Cl>[K].C1(C(O)=O)C2=C3C(C4C5C(=CC=CC2=5)C=CC=4)=CC=C(C(O)=O)C3=C(C(O)=O)C=1C(O)=O.[OH-].[K+].C(O)(C)C>[CH:36]1[C:37]2=[C:40]3[C:29]([C:28]4[C:39]5[C:24](=[CH:23][CH:22]=[CH:21][C:38]2=5)[CH:25]=[CH:26][CH:27]=4)=[CH:30][CH:31]=[CH:32][C:33]3=[CH:34][CH:35]=1
参加物実験手順後処理出典と根拠反応ノート

参加物

9

反応物 4

HCID 313Hydrochloric AcidHCID 5281Stearic AcidHCID 15793OctadecylamineHCID 86737471HCID 86737471、化合物

生成物 1

HCID 9142Perylene

試薬・触媒・溶媒 4

HCID 3776Isopropanol溶媒
HCID 14797
Potassium Hydroxide
溶媒
2 回
HCID 5462222Potassium溶媒
HCID 19063515Perylene-1,2,3,4-tetracarboxylic acid溶媒

実験手順

27.4 parts of crude perylenetetracarboxylic dianhydride in the form of the potassium salt of perylenetetracarboxylic acid are dissolved in aqueous potassium hydroxide solution as described in Example 1. To this solution are added 2 parts of stearic acid, dissolved in 60 parts by volume of 1% potassium hydroxide solution. With stirring, the alkaline perylenetetracarboxylic acid/stearic acid solution is added dropwise in the course of 15 minutes at 60° C. to a suspension consisting of 1.4 parts of MgCl2.6H2O, 0.7 parts of stearylamine, 35 parts by volume of about 37% aqueous hydrochloric acid and 60 parts by volume of isopropanol. The formation of the anhydride imide is brought to completion by stirring the acid suspension for 31/2 hours at reflux temperature. The red pigment suspension is then filtered at about 70° C. The filter cake is washed neutral with cold water and dried in a vacuum cabinet at 80° C., affording 29.8 parts of a perylene pigment with properties as good as those of the pigment of Example 1.

後処理

  1. stirringby stirring the acid suspension for 31/2 hours
  2. temperatureat reflux temperature
  3. filtrationThe red pigment suspension is then filtered at about 70° C
  4. washThe filter cake is washed neutral with cold water
  5. customdried in a vacuum cabinet at 80° C.

出典と根拠

ORDレコード
ord-87b70f3364c44a2c930935bdf9f06233
出典データセット
uspto-grants-1981_02
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04250079

反応ノート

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