Methanol → 4-(2-Methoxyethoxy)benzene-1,2-diamine
反応式
[N+:1]([C:4]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][CH2:13][O:14][CH3:15])=[CH:7][C:5]=1[NH2:6])([O-])=O.CO.C(=O)([O-])[O-].[Na+].[Na+].S(S([O-])=O)([O-])=O.[Na+].[Na+]>O>[NH2:1][C:4]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][CH2:13][O:14][CH3:15])=[CH:7][C:5]=1[NH2:6]参加物
6
実験手順
A mixture of 11 g. of 2-nitro-5-(2-methoxyethoxy) aniline, 220 ml. of methanol, 460 ml. of water, 40 g. sodium carbonate and 60 g. sodium hydrosulfite is refluxed for 15 minutes. The solution is concentrated, diluted with water and extracted with chloroform. Evaporation of the chloroform leaves 1,2-diamino-4-(2-methoxyethoxy) benzene as an oil, sufficiently pure for the next step.
後処理
- additionA mixture of 11 g
- concentrationThe solution is concentrated
- additiondiluted with water
- extractionextracted with chloroform
- customEvaporation of the chloroform
出典と根拠
- ORDレコード
- ord-e70dd23206a944d88fb6d64a853964fd
- 出典データセット
- uspto-grants-1977_01
- 特許番号
- US04002640
反応ノート
読み込み中…