Diaminostilbenedisulfonic acid → Disodium 4,4'-bis(4,6-dichloro-s-triazin-2-ylamino)-2,2'-stilbenedisulfonate

HRID 1415380

反応式

HRID 1415380 の反応式
[NH2:1][C:2]1[CH:3]=[C:4]([S:21]([OH:24])(=[O:23])=[O:22])[C:5]([CH:8]=[CH:9][C:10]2[C:11]([S:17]([OH:20])(=[O:19])=[O:18])=[CH:12][C:13]([NH2:16])=[CH:14][CH:15]=2)=[CH:6][CH:7]=1.[N:25]1[C:32]([Cl:33])=[N:31][C:29]([Cl:30])=[N:28][C:26]=1Cl.[OH-].[Na+:35]>CC(C)=O>[Cl:30][C:29]1[N:31]=[C:32]([Cl:33])[N:25]=[C:26]([NH:1][C:2]2[CH:3]=[C:4]([S:21]([O-:24])(=[O:23])=[O:22])[C:5]([CH:8]=[CH:9][C:10]3[C:11]([S:17]([O-:20])(=[O:19])=[O:18])=[CH:12][C:13]([NH:16][C:26]4[N:25]=[C:32]([Cl:33])[N:31]=[C:29]([Cl:30])[N:28]=4)=[CH:14][CH:15]=3)=[CH:6][CH:7]=2)[N:28]=1.[Na+:35].[Na+:35]

参加物

5

反応物 3

HCID 6668Diaminostilbenedisulfonic acidHCID 7954Cyanuric chlorideHCID 14798Sodium Hydroxide

生成物 1

HCID 73156169Disodium 4,4'-bis(4,6-dichloro-s-triazin-2-ylamino)-2,2'-stilbenedisulfonate

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

Disodium 4,4'-bis(4,6-dichloro-s-triazin-2-ylamino)-2,2'-stilbenedisulfonate was prepared by interaction of 500 pounds of 4,4'-diamino-2,2'-stilbenedisulfonic acid with a solution of 500 pounds of cyanuric chloride in 2100 pounds of acetone in an aqueous reaction medium at pH 7-8 prepared by mixing 3200 pounds of crushed ice and approximately 2100 pounds of 10 percent aqueous sodium hydroxide solution. The disodium 4,4'-bis(4,6-dichloro-s-triazin-2-ylamino)-2,2'-stilbenedisulfonate thus obtained was mixed with 270 pounds of disodium phosphate and interacted at 15°-50° C with 625 pounds of aniline for thirty minutes and then the pH of the reaction mixture was adjusted to 6.7-6.8 by adding approximately 600 pounds of 10 percent aqueous sodium hydroxide solution during a period of one hour.

後処理

  1. customprepared

出典と根拠

ORDレコード
ord-d691670d41ec4111b22420a5248cbde1
出典データセット
uspto-grants-1977_01
特許番号
US04005026

関連ノート

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