Hydrochloric Acid → Di(tetrachlorophenyl)tetrachlorocyclopentadiene

HRID 1415487

反応式

HRID 1415487 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([Cl:8])=[C:4]([Cl:9])[C:3]=1[Cl:10].Cl[C:12]1(Cl)[C:16]([Cl:17])=[C:15]([Cl:18])[C:14]([Cl:19])=[C:13]1[Cl:20].[Cl-:22].[Al+3].[Cl-:24].[Cl-:25].[ClH:26]>>[Cl:1][C:2]1[C:3]([Cl:10])=[C:4]([Cl:9])[C:5]([Cl:8])=[C:6]([C:12]2([C:2]3[CH:7]=[C:6]([Cl:22])[C:5]([Cl:24])=[C:4]([Cl:25])[C:3]=3[Cl:26])[C:13]([Cl:20])=[C:14]([Cl:19])[C:15]([Cl:18])=[C:16]2[Cl:17])[CH:7]=1

参加物

5

反応物 4

HCID 313Hydrochloric AcidHCID 6478HexachlorocyclopentadieneHCID 124631,2,3,4-TetrachlorobenzeneHCID 6451240Aluminum(III) Chloride

生成物 1

HCID 54039303Di(tetrachlorophenyl)tetrachlorocyclopentadiene

実験手順

A mixture of 1,2,3,4-tetrachlorobenzene, 130 grams (0.6 mole), hexachlorocyclopentadiene, 65 grams (0.24 mole), and aluminum chloride, 5 grams, was heated on a steam bath at 75°-90° centigrade until the evolution of hydrogen chloride stopped and the reaction mixture solidified. The purple solid was triturated with acetone to dissolve the aluminum chloride, filtered, washed with acetone and dried to give a tan, solid product.

後処理

  1. customThe purple solid was triturated with acetone
  2. dissolutionto dissolve the aluminum chloride
  3. filtrationfiltered
  4. washwashed with acetone
  5. customdried
  6. customto give a tan, solid product

出典と根拠

ORDレコード
ord-b9208cc0342340e587b3093fb7374cf0
出典データセット
uspto-grants-1977_01
特許番号
US04005153

関連ノート

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