Trimethylsilyl cyanide → HCID 21862809、化合物

反応式

[CH3:1][C:2]1[CH:19]=[CH:18][C:5]([CH:6]=[N:7][C:8]2[CH:13]=[CH:12][C:11]([S:14](=[O:17])(=[O:16])[NH2:15])=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.C[Si]([C:24]#[N:25])(C)C>>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([CH:6]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([S:14](=[O:16])(=[O:17])[NH2:15])=[CH:10][CH:9]=2)[C:24]#[N:25])=[CH:18][CH:19]=1

参加物

反応物 2

HCID 82115Trimethylsilyl cyanide

HCID 690836HCID 690836、化合物

生成物 1

HCID 21862809HCID 21862809、化合物

実験手順

Following a procedure similar to that described in Example 1(ii), but using N-(4-methylbenzylidene)-4-sulfamoylaniline [prepared as described in step (i) above] and trimethylsilyl cyanide as starting materials, the title compound was obtained as a white powder (yield 94%).

出典と根拠

ORDレコード: ord-cd7e54d5022b464e9e7b62f6c6f1aacf
出典データセット: uspto-grants-1999_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05908858

反応ノート

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