Methylhydrazine → HCID 178481940、化合物
反応式
[C:1]1(=O)[O:6][C:4](=[O:5])[C:3]2=[CH:7][CH:8]=[CH:9][CH:10]=[C:2]12.[CH3:12][NH:13][NH2:14]>C(O)(=O)C.O>[OH:6][C:1]1[C:2]2[C:3](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:4](=[O:5])[N:13]([CH3:12])[N:14]=1参加物
5
実験手順
Phthalic anhydride (7.4 g) was dissolved in hot acetic acid (50 ml) and a solution of methylhydrazine (2.7 ml) in water (50 ml) was added. The mixture was heated under reflux for 15 minutes and left to cool overnight. The precipitate that formed was filtered off, washed with water and dried under reduced pressure at 65° C. to yield 1,2-dihydro-4-hydroxy-2-methyl-1-oxophthalazin (7.6 g) as a white solid. m.p. 243-244° C.
後処理
- temperatureThe mixture was heated
- temperatureunder reflux for 15 minutes
- waitleft
- temperatureto cool overnight
- customThe precipitate that formed
- filtrationwas filtered off
- washwashed with water
- customdried under reduced pressure at 65° C.
出典と根拠
- ORDレコード
- ord-d15553d57ff64044a7df816ee8f6a5c2
- 出典データセット
- uspto-grants-2000_06
- 特許番号
- US06071938
反応ノート
読み込み中…