Potassium Nitrate → HCID 18706433、化合物

HRID 1422212ノート

反応式

HRID 1422212 の反応式
[Br:1][C:2]1[CH:11]=[C:10]2[C:5]([N:6]=[C:7]([O:14][CH3:15])[C:8]([O:12][CH3:13])=[N:9]2)=[C:4]([CH2:16][Br:17])[CH:3]=1.[N+:18]([O-])([O-:20])=[O:19].[K+]>S(=O)(=O)(O)O>[Br:1][C:2]1[C:11]([N+:18]([O-:20])=[O:19])=[C:10]2[C:5]([N:6]=[C:7]([O:14][CH3:15])[C:8]([O:12][CH3:13])=[N:9]2)=[C:4]([CH2:16][Br:17])[CH:3]=1

参加物

4

反応物 2

HCID 24434Potassium NitrateHCID 23298010HCID 23298010、化合物

生成物 1

HCID 18706433HCID 18706433、化合物

試薬・触媒・溶媒 1

HCID 1118Sulfuric Acid溶媒

反応条件

温度
20 °C

実験手順

20 ml of sulfuric acid are cooled to 0° C. and then 5 g (13.8 mmol) of 7-bromo-5-bromomethyl-2,3-dimethoxy-quinoxaline are added. After a further 15 minutes, 1.46 g (1.05 equiv.) of potassium nitrate are added and the mixture is stirred for 15 hours at 20° C. The mixture is poured onto ice, and the solid is filtered off and washed with water. The title compound is obtained in the form of a beige solid.

後処理

  1. additionThe mixture is poured onto ice
  2. filtrationthe solid is filtered off
  3. washwashed with water

出典と根拠

ORDレコード
ord-cfe9b306f43c472ea1c7d5ecce923c92
出典データセット
uspto-grants-2000_06
特許番号
US06080743

反応ノート

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