Benzene → 2-Methyl-1-phenyl-2-propen-1-one

HRID 1428433ノート

反応式

HRID 1428433 の反応式
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:7](Cl)(=[O:11])[C:8]([CH3:10])=[CH2:9].[Cl-].[Al+3].[Cl-].[Cl-]>C(=S)=S>[C:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)(=[O:11])[C:8]([CH3:10])=[CH2:9]

参加物

5

反応物 3

HCID 241BenzeneHCID 13528Methacryloyl chlorideHCID 6451240Aluminum(III) Chloride

生成物 1

HCID 2636662-Methyl-1-phenyl-2-propen-1-one

試薬・触媒・溶媒 1

HCID 6348Carbon Disulfide溶媒

実験手順

Benzene (1 mL), methacryloyl chloride (0.156 mg), and aluminium chloride (199 mg) were reacted in carbon disulfide (2 mL) at from 0° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (106 mg).

後処理

  1. additionThe resultant was treated in the same manner

出典と根拠

ORDレコード
ord-1db898b1c6e94443a386b9da369b089f
出典データセット
uspto-grants-2015_01
特許番号
US08937091B2

反応ノート

読み込み中…