5-Tert-butyl-m-xylene → 2,6-Dimethyl-4-t-butyl-1-acryloylbenzene

HRID 1428456

反応式

HRID 1428456 の反応式
[C:1]([C:5]1[CH:6]=[C:7]([CH3:12])[CH:8]=[C:9]([CH3:11])[CH:10]=1)([CH3:4])([CH3:3])[CH3:2].[C:13](Cl)(=[O:16])[CH:14]=[CH2:15].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[CH3:12][C:7]1[CH:6]=[C:5]([C:1]([CH3:4])([CH3:3])[CH3:2])[CH:10]=[C:9]([CH3:11])[C:8]=1[C:13](=[O:16])[CH:14]=[CH2:15]

参加物

5

反応物 3

HCID 73785-Tert-butyl-m-xyleneHCID 13140Acryloyl chlorideHCID 6451240Aluminum(III) Chloride

生成物 1

HCID 469134822,6-Dimethyl-4-t-butyl-1-acryloylbenzene

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

5-t-butylmetaxylene (0.5 mL), acryloyl chloride (120 mg), and aluminium chloride (150 mg) were reacted in dichloromethane (1.5 mL) at from −40° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (120 mg).

後処理

  1. additionThe resultant was treated in the same manner

出典と根拠

ORDレコード
ord-1f38244b93d54d9a9df49f23e0d57e56
出典データセット
uspto-grants-2015_01
特許番号
US08937091B2

関連ノート

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