Manganese → gamma-Cyclodextrin Manganese

HRID 1428696

反応式

HRID 1428696 の反応式
[Mn:1].[CH2:2]([OH:88])[C@H:3]1[O:8][C@@H:7]2[O:9][C@H:10]3[C@H:15]([OH:16])[C@@H:14]([OH:17])[C@@H:13]([O:18][C@H:19]4[C@H:24]([OH:25])[C@@H:23]([OH:26])[C@@H:22]([O:27][C@H:28]5[C@H:33]([OH:34])[C@@H:32]([OH:35])[CH:31]([O:36][CH:37]6[C@H:42]([OH:43])[C@@H:41]([OH:44])[CH:40]([CH:45]7[C@H:50]([OH:51])[C@@H:49]([OH:52])[CH:48]([O:53][C@H:54]8[C@H:59]([OH:60])[C@@H:58]([OH:61])[C@@H:57]([O:62][C@H:63]9[C@H:69]([OH:70])[C@@H:68]([OH:71])[C@@H:66]([O:67][C@H:4]1[C@H:5]([OH:87])[C@H:6]2[OH:86])[O:65][C@@H:64]9[CH2:72][OH:73])[O:56][C@@H:55]8[CH2:74][OH:75])[O:47][C@@H:46]7[CH2:76][OH:77])[O:39][C@@H:38]6[CH2:78][OH:79])[O:30][C@@H:29]5[CH2:80][OH:81])[O:21][C@@H:20]4[CH2:82][OH:83])[O:12][C@@H:11]3[CH2:84][OH:85]>>[CH2:2]([OH:88])[C@H:3]1[O:8][C@@H:7]2[O:9][C@H:10]3[C@H:15]([OH:16])[C@@H:14]([OH:17])[C@@H:13]([O:18][C@H:19]4[C@H:24]([OH:25])[C@@H:23]([OH:26])[C@@H:22]([O:27][C@H:28]5[C@H:33]([OH:34])[C@@H:32]([OH:35])[CH:31]([O:36][CH:37]6[C@H:42]([OH:43])[C@@H:41]([OH:44])[CH:40]([CH:45]7[C@H:50]([OH:51])[C@@H:49]([OH:52])[CH:48]([O:53][C@H:54]8[C@H:59]([OH:60])[C@@H:58]([OH:61])[C@@H:57]([O:62][C@H:63]9[C@H:69]([OH:70])[C@@H:68]([OH:71])[C@@H:66]([O:67][C@H:4]1[C@H:5]([OH:87])[C@H:6]2[OH:86])[O:65][C@@H:64]9[CH2:72][OH:73])[O:56][C@@H:55]8[CH2:74][OH:75])[O:47][C@@H:46]7[CH2:76][OH:77])[O:39][C@@H:38]6[CH2:78][OH:79])[O:30][C@@H:29]5[CH2:80][OH:81])[O:21][C@@H:20]4[CH2:82][OH:83])[O:12][C@@H:11]3[CH2:84][OH:85].[Mn:1]

参加物

3

反応物 2

HCID 23930Manganese2 回HCID 44431027gamma-Cyclodextrine

生成物 1

HCID 131732361gamma-Cyclodextrin Manganese

実験手順

23 g of a manganese-based drier, Manganese CEM-ALL® 12% solution (OM Group, Inc.) was added to the above-noted γ-cylodextrin solution. A brown precipitate formed upon addition of the drier. The mixture was stirred for at least 16 hours. The precipitate was filtered off under reduced pressure. The filtrate was light yellow coloured. The precipitate was dried under reduced pressure (around 19 InHg) at 50-60° C. The FTIR spectrum of the resultant inclusion complex is provided in FIG. 1(d).

後処理

  1. customA brown precipitate formed upon addition of the drier
  2. filtrationThe precipitate was filtered off under reduced pressure
  3. dry with materialThe precipitate was dried under reduced pressure (around 19 InHg) at 50-60° C
  4. customThe FTIR spectrum of the resultant inclusion complex is provided in FIG. 1(d)

出典と根拠

ORDレコード
ord-be88e115df0e4cc88356a4c07548ff8c
出典データセット
uspto-grants-2015_01
特許番号
US08937119B2

関連ノート

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