Magnesium ethanolate → HCID 178525631、化合物
反応式
[C:1]([O:7][CH2:8][CH3:9])(=[O:6])[CH2:2][C:3]([O-:5])=[O:4].[O-]CC.[Mg+2:13].[O-]CC>C1COCC1>[C:1]([O-:7])(=[O:6])[CH2:2][C:3]([O-:5])=[O:4].[CH2:8]([Mg+2:13])[CH3:9]参加物
4
実験手順
To a stirred solution of monoethyl malonate 1(1.65 g, 12.5 mmol) in THF (25 mL) was added the magnesium ethoxide (0.61 g, 6.25 mmol). The reaction mixture was allowed to stir at rt for 5 h (until the solution become clear). The result solution was used for next step without any treatment.
出典と根拠
- ORDレコード
- ord-6bf30d76f105458abf336a2d91aa06a1
- 出典データセット
- uspto-grants-2015_01
- 特許番号
- US08940506B2
反応ノート
読み込み中…