6-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate → 7-Methoxy-3-(4-methoxy-2-nitrophenyl)-1,2-dihydronaphthalene

HRID 1433862

反応式

HRID 1433862 の反応式
FC(F)(F)S(O[C:7]1[CH2:16][CH2:15][C:14]2[C:9](=[CH:10][CH:11]=[C:12]([O:17][CH3:18])[CH:13]=2)[CH:8]=1)(=O)=O.C([Sn](CCCC)(CCCC)[C:26]1[CH:31]=[CH:30][C:29]([O:32][CH3:33])=[CH:28][C:27]=1[N+:34]([O-:36])=[O:35])CCC>>[CH3:18][O:17][C:12]1[CH:13]=[C:14]2[C:9]([CH:8]=[C:7]([C:26]3[CH:31]=[CH:30][C:29]([O:32][CH3:33])=[CH:28][C:27]=3[N+:34]([O-:36])=[O:35])[CH2:16][CH2:15]2)=[CH:10][CH:11]=1

参加物

3

反応物 2

HCID 153302566-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonateHCID 23087474Tributyl(4-methoxy-2-nitrophenyl)tin

生成物 1

HCID 230871417-Methoxy-3-(4-methoxy-2-nitrophenyl)-1,2-dihydronaphthalene収率 73.2%

実験手順

Synthesized from 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.3 g) and tributyl(4-methoxy-2-nitrophenyl)tin (3.9 g) according to an analogous synthetic method to Preparation Example 77, the title compound (1.7 g) was obtained.

後処理

  1. customaccording to an analogous synthetic method to Preparation Example 77

出典と根拠

ORDレコード
ord-93695c5539284e51b554a25583905b0f
出典データセット
uspto-grants-2009_11
特許番号
US07612114B2

関連ノート

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