Cyclohexanone → (1,1'-Biphenyl)-2-ol

HRID 1439625

反応式

HRID 1439625 の反応式
S([O-])([O-])(=O)=O.[K+].[K+].[C:8]1(=[O:14])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1>O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Cl-].[Pt+4].Cl[Pd]>[C:8]1([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=2[OH:14])[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1

参加物

5

反応物 2

HCID 7967CyclohexanoneHCID 24507Potassium Sulfate2 回

生成物 1

HCID 7017(1,1'-Biphenyl)-2-ol

試薬・触媒・溶媒 2

HCID 73357391Platinum(4+);tetrachloride;hexahydrate触媒HCID 178479784chloropalladium触媒

実験手順

The same procedure as in Example 1 is repeated except that in place of 1g of chloroplatinic acid hexahydrate, 2.5g of potassium sulfate and at a rate of 15.5 ml/hr. of cyclohexanone dimer, 1.25g of chloropalladium, 2.0g of potassium sulfate and at a rate of 8.0 ml/hr. are employed. The conversion is found to be always 100% over the reaction period of 2,000 hours. Table 2 gives the selectivity for o-phenylphenol measured.

後処理

  1. customover the reaction period of 2,000 hours

出典と根拠

ORDレコード
ord-958bc36869534ee69a17a532487e72c8
出典データセット
uspto-grants-1977_11
特許番号
US04060559

関連ノート

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