HCID 13205870、化合物 → HCID 13205871、化合物
反応式
[CH:1]([N:4]([CH:9]1[CH:23]=[C:22]([CH3:24])[CH2:21][CH:20]=[C:10]1[C:11]([C:13]1[CH:18]=[CH:17][C:16]([F:19])=[CH:15][CH:14]=1)=[O:12])[C:5]([O:7][CH3:8])=[O:6])([CH3:3])[CH3:2]>C(Cl)(Cl)Cl.[O-2].[O-2].[Mn+4]>[CH:1]([N:4]([C:9]1[CH:23]=[C:22]([CH3:24])[CH:21]=[CH:20][C:10]=1[C:11]([C:13]1[CH:18]=[CH:17][C:16]([F:19])=[CH:15][CH:14]=1)=[O:12])[C:5]([O:7][CH3:8])=[O:6])([CH3:3])[CH3:2]参加物
4
実験手順
20 g 2-(N-isopropyl-N-carbomethoxyamino)-4-methyl-4'-fluoro-2,5-dihydrobenzophenone and 100 g manganese dioxide in 200 ml chloroform are stirred 4 hours under reflux. The reaction mixture is cooled, filtered and evaporated in vacuo. The residue is recrystallised from hexane to obtain the heading compound, m.p. 92°-94° C.
後処理
- temperatureunder reflux
- temperature