Peracetic Acid → Phenyl acetate

反応式

[C:1]([O-:4])(=[O:3])[CH3:2].[C:5]1([Sn+](C2C=CC=CC=2)C2C=CC=CC=2)[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.CC(O[Hg]C1C=CC=CC=1)=O.C(OO)(=O)C>>[C:1]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)(=[O:3])[CH3:2]

参加物

反応物 3

HCID 6585Peracetic Acid

HCID 9909408Triphenyltin hydroxide acetate

HCID 16682730Phenylmercuric Acetate

生成物 1

HCID 31229Phenyl acetate収率 58%

実験手順

The procedure of Example 1 is repeated except that 5 mmols of triphenyl tin acetate are employed instead of the phenyl mercuric acetate of Example 1, and 30 mmols of peracetic acid is used. After 4 hours of reaction at 75° C. there is obtained phenyl acetate in a yield of about 58%, and in a selectivity of about 68%, at a triphenyl tin acetate conversion of about 85%.