Phenylmercuric Acetate → Phenyl acetate

HRID 1447207

反応式

HRID 1447207 の反応式
CC(O[Hg]C1C=CC=CC=1)=O.[C:12]([O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:14])[CH3:13].C(OI=O)(=O)C>C(O)(=O)C>[C:12]([O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:14])[CH3:13]

参加物

4

反応物 2

HCID 16682730Phenylmercuric AcetateHCID 86738254Phenyl iodoso diacetate

生成物 1

HCID 31229Phenyl acetate

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

The procedure of Example 3 is repeated except that only 10 ml. of acetic acid is charged to the reaction vessel, thereby increasing the concentration of the phenyl mercuric acetate and phenyl iodoso diacetate reactants in the liquid. At the end of the 0.25 hour of reaction at 120° C., phenyl acetate yield is found to be increased to 68%, at a phenyl mercuric acetate conversion of about 72% and a phenyl acetate selectivity of about 94%.

後処理

  1. customAt the end of the 0.25 hour of reaction at 120° C.

出典と根拠

ORDレコード
ord-a28dddae7f5f4de8b751370c240c3100
出典データセット
uspto-grants-1982_02
特許番号
US04316046

関連ノート

読み込み中…