Azobisisobutyronitrile → Vinylacetamide vinylsulfonate

HRID 1447827

反応式

HRID 1447827 の反応式
[C:1]([NH:4]C=C)(=[O:3])[CH3:2].[CH:7]([S:9]([O-:12])(=[O:11])=[O:10])=[CH2:8].CC(N=NC(C#N)(C)C)(C#N)C>>[CH:7]([CH2:2][C:1]([NH2:4])=[O:3])=[CH2:8].[CH:7]([S:9]([O-:12])(=[O:11])=[O:10])=[CH2:8]

参加物

4

反応物 3

HCID 6547AzobisisobutyronitrileHCID 78875N-VinylacetamideHCID 4644996Vinylsulfonate

生成物 1

HCID 86736729Vinylacetamide vinylsulfonate

反応条件

温度
75 °C

実験手順

Acetamidoethylene monomer prepared in Part A (5 moles) is added to a 5 liter agitated reactor along with 2.7 moles of vinylsulfonate (sodium salt) and 16 g of AIBN. The materials are placed in a 5 liter reaction flask and heated to 75° C. while d oxygenating the flask. Temperature is increased to 80° C. and held there for 180 minutes. The reaction mixture, a solution of a copolymer of vinylacetamide and vinylsulfonate, is dissolved in water. This solution is purified by filtration and ultrafiltration in an Amicon ultrafiltration unit in the presence of added NaCl. Low molecular weight impurities are removed leaving a solution of vinylacetamide-vinylsulfonate as retentate.

後処理

  1. additionis added to a 5 liter
  2. customThe materials are placed in a 5 liter reaction flask
  3. customwhile d oxygenating the flask
  4. temperatureTemperature is increased to 80° C.
  5. dissolutionThe reaction mixture, a solution of a copolymer of vinylacetamide and vinylsulfonate, is dissolved in water
  6. filtrationThis solution is purified by filtration and ultrafiltration in an Amicon ultrafiltration unit in the presence of added NaCl
  7. customLow molecular weight impurities are removed

出典と根拠

ORDレコード
ord-0a7d9e7003a546e89325c5b62141d83a
出典データセット
uspto-grants-1979_12
特許番号
US04178422

関連ノート

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