Acetic Acid → HCID 54161447、化合物
反応式
[CH3:1][O:2][C:3]([C:5]1[NH:6][C:7]2[C:12]([C:13]=1[O:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=1[N+:21]([O-])=O)=[CH:11][CH:10]=[CH:9][CH:8]=2)=[O:4].C(O)(=O)C>[Fe].C(O)C>[CH3:1][O:2][C:3]([C:5]1[NH:6][C:7]2[C:12]([C:13]=1[O:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=1[NH2:21])=[CH:11][CH:10]=[CH:9][CH:8]=2)=[O:4]参加物
5
実験手順
A mixture of 3.12 g of methyl-3-[o-nitrophenoxy]-indole-2-carboxylate, 10 g of 40 mesh iron filings, 5 ml of 5% aqueous acetic acid and 300 ml of ethanol was refluxed with stirring for 3 hours. The mixture was filtered and concentrated to a solid. Recrystallization from ethanol gave analytical material, mp. 183°-4°.
後処理
- temperaturewas refluxed
- filtrationThe mixture was filtered
- concentrationconcentrated to a solid
- customRecrystallization from ethanol
- customgave analytical material, mp. 183°-4°
出典と根拠
- ORDレコード
- ord-11c4c3cd6cff4c83be6feea022713345
- 出典データセット
- uspto-grants-1979_12
- 特許番号
- US04179513
反応ノート
読み込み中…