1-Butanol → Butyl 4-(tert-butylperoxy)-4-methylpentan-2-yl carbonate
反応式
C([OH:5])CCC.N1C=[CH:10][CH:9]=[CH:8][CH:7]=1.Cl[C:13]([O:15][CH:16]([CH3:27])[CH2:17][C:18]([CH3:26])([O:20][O:21][C:22]([CH3:25])([CH3:24])[CH3:23])[CH3:19])=[O:14]>C(OCC)C>[C:13](=[O:5])([O:14][CH2:7][CH2:8][CH2:9][CH3:10])[O:15][CH:16]([CH3:27])[CH2:17][C:18]([CH3:26])([O:20][O:21][C:22]([CH3:25])([CH3:24])[CH3:23])[CH3:19]参加物
5
実験手順
To a solution of 8.1 g. (0.11 mole) of n-butyl alcohol and 7.9 g. (0.1 mole) of pyridine in diethyl ether cooled to 10°±1° C. was added a solution of 27.0 g. (0.1 mole) 1,3-dimethyl-3-(t-butylperoxy)butyl chloroformate. The reaction temperature was controlled at 15°±1° C. during the addition.
後処理
- additionwas added a solution of 27.0 g
- additionThe reaction temperature was controlled at 15°±1° C. during the addition
出典と根拠
- ORDレコード
- ord-ce5598552d554ba4a491b9b6a5f9c3cc
- 出典データセット
- uspto-grants-1979_12
- 特許番号
- US04180518
反応ノート
読み込み中…