Ethanol → 1,3-Dimethyl-3-(ethoxycarbonylperoxy)butyl ethyl carbonate
反応式
Cl[C:2]([O:4][CH:5]([CH3:17])[CH2:6][C:7]([CH3:16])([O:9][O:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])[CH3:8])=[O:3].C([OH:20])C.N1[CH:26]=[CH:25]C=CC=1>C(OCC)C>[C:2](=[O:20])([O:3][CH2:25][CH3:26])[O:4][CH:5]([CH3:17])[CH2:6][C:7]([CH3:16])([O:9][O:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])[CH3:8]参加物
5
実験手順
To a solution of 24.4 g. (0.0786 mole) of (86.4%) 1,3-dimethyl-3(ethoxycarbonylperoxy)butyl chloroformate in 100 ml of diethyl ether, cooled at 10°±1° C. was added a solution of 4.6 g (0.1 mole) of ethanol and 7.9 g. (0.1 mole) of pyridine in 25 ml of diethyl ether over a period of 20 minutes.
出典と根拠
- ORDレコード
- ord-8f71e5df8422481e8193df0a7d71116a
- 出典データセット
- uspto-grants-1979_12
- 特許番号
- US04180518
反応ノート
読み込み中…