2-Ethylhexanol → 2-ethylhexyl N-methacryloylcarbamate

HRID 1452124

反応式

HRID 1452124 の反応式
[C:1]([NH:6][C:7](=O)[O:8]CC)(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH2:12]([CH:14]([CH2:17][CH2:18][CH2:19][CH3:20])[CH2:15][OH:16])[CH3:13]>C1(C=CC(O)=CC=1)O>[C:1]([NH:6][C:7](=[O:8])[O:16][CH2:15][CH:14]([CH2:12][CH3:13])[CH2:17][CH2:18][CH2:19][CH3:20])(=[O:5])[C:2]([CH3:4])=[CH2:3]

参加物

4

反応物 2

HCID 77202-EthylhexanolHCID 13628540Ethyl (2-methylacryloyl)carbamate

生成物 1

HCID 199736832-ethylhexyl N-methacryloylcarbamate収率 72.2%

試薬・触媒・溶媒 1

HCID 785Hydroquinone触媒

反応条件

温度
120 °C

実験手順

A reaction vessel was charged with 15.7 g of ethyl N-methacryloylcarbamate and 52 g of 2-ethylhexyl alcohol, to which 0.1 g of hydroquinone was added and heated at 120° C. for one hour. The resulting mixture was condensed under reduced pressure and isolated by column chromatography to obtain 17.4 g of 2-ethylhexyl N-methacryloylcarbamate having a viscosity of 800 cp.

後処理

  1. additionwas added
  2. customcondensed under reduced pressure
  3. customisolated by column chromatography

出典と根拠

ORDレコード
ord-db2484a96fec493cb3de5b738a92ebcb
出典データセット
uspto-grants-1997_02
特許番号
US05606096

関連ノート

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