AC1Mbfzi → HCID 11273668、化合物
反応式
[N:1]([C@@H:4]1[O:41][C@H:40]([CH2:42][O:43][C:44](=[O:46])[CH3:45])[C@@H:15]([O:16][C@@H:17]2[O:34][C@H:33]([CH2:35][O:36][C:37](=[O:39])[CH3:38])[C@@H:28]([O:29][C:30](=[O:32])[CH3:31])[C@H:23]([O:24][C:25](=[O:27])[CH3:26])[C@H:18]2[O:19][C:20](=[O:22])[CH3:21])[C@H:10]([O:11][C:12](=[O:14])[CH3:13])[C@H:5]1[O:6][C:7](=[O:9])[CH3:8])=[N+]=[N-]>C(OCC)(=O)C.[Pd]>[NH2:1][C@@H:4]1[O:41][C@H:40]([CH2:42][O:43][C:44](=[O:46])[CH3:45])[C@@H:15]([O:16][C@@H:17]2[O:34][C@H:33]([CH2:35][O:36][C:37](=[O:39])[CH3:38])[C@@H:28]([O:29][C:30](=[O:32])[CH3:31])[C@H:23]([O:24][C:25](=[O:27])[CH3:26])[C@H:18]2[O:19][C:20](=[O:22])[CH3:21])[C@H:10]([O:11][C:12](=[O:14])[CH3:13])[C@H:5]1[O:6][C:7](=[O:9])[CH3:8]参加物
4
実験手順
A solution of 35 (0.67 g) in ethyl acetate (15 ml) was hydrogenated in the presence of Pd-C (0.3 g) at atmospheric pressure for one hour. Pd-C was filtered, and the solvent was evaporated to give 1-amino-1-deoxy-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1→4)-2,3,6-tri-O-acetyl-β-D-glucopyranose (36, 0.64 g, 100%).