Vinyl Acetate → Trimethylolpropane

HRID 1461221

反応式

HRID 1461221 の反応式
CC([O:4][CH:5]=[CH2:6])=O.C=[CH:8][OH:9].C=[CH:11][O:12]COC=C.[C:17](OC=C)(=O)[CH3:18].C(O)=C.OC1C=CC(C)=CC=1N1N=C2C=CC=CC2=N1>C([O-])(=O)CCCCCCCCCCCCCCCCC.[Zn+2].C([O-])(=O)CCCCCCCCCCCCCCCCC.[O-2].[O-2].[Cr+4].O1CCCC1>[CH2:11]([C:6]([CH2:5][OH:4])([CH2:8][OH:9])[CH2:17][CH3:18])[OH:12]

参加物

8

反応物 4

HCID 7904Vinyl AcetateHCID 11199Vinyl alcoholHCID 17113DrometrizoleHCID 173927Ethenol;ethenoxymethoxyethene;ethenyl acetate2 回

生成物 1

HCID 6510Trimethylolpropane

試薬・触媒・溶媒 3

HCID 11178Zinc Stearate触媒HCID 73415796Chromium dioxide触媒HCID 8028Tetrahydrofuran溶媒

実験手順

100,000 parts of steel balls, 5,000 parts of the 12.5% strength solution of the polyurethane elastomer stated in Example A, 3,000 parts of a 10% strength solution of a polyvinylformal, consisting of 82% of vinylformal, 12% of vinyl acetate and 6% of vinyl alcohol units, 135 parts of N-tallow fat-1,3-diaminodioleate, 270 parts of zinc stearate, 40 parts of polyisobutene (C24 -C28), 185 parts of 2-(2-hydroxy-5-methylphenyl)-2H-benzotriazole and 13,500 parts of a ferromagnetic chromium dioxide pigment having a mean particle size of 0.5 μm and a length/width ratio of 4:1 and 4,500 parts of tetrahydrofuran were introduced into a steel ball mill having a capacity of 100,000 parts by volume, and dispersing was carried out for 70 hours. Thereafter, 11,000 parts (12.5% strength) of polymer A and 7,000 parts of the stated 10% strength polyvinylformal solution were added and dispersing was continued for a further 20 hours. The dispersion was then removed from the mill and filtered under pressure through a filter having a pore diameter of 5 μm. After the filtration process, 17 g of a 50% strength solution of a triisocyanate, obtained from 3 moles of toluylenediisocyanate and 1 mole of trimethylolpropane, were added per kg of dispersion with vigorous stirring. The dispersion was then applied to an 8 μm thick polyethylene terephthalate film by means of a conventional knife coater. The coated film was passed through a magnetic field to orient the magnetic particles and then dried at from 50° to 90° C. After drying, the magnetic layer was compacted and calendered, so that it was 5 μm thick. The coated film was then slit into 3.8=1 mm wide tapes.

後処理

  1. additiondispersing
  2. additiondispersing
  3. waitwas continued for a further 20 hours
  4. customThe dispersion was then removed from the mill
  5. filtrationfiltered under pressure through a filter

出典と根拠

ORDレコード
ord-2bdc045067874419967d9dad057be8f2
出典データセット
uspto-grants-1991_12
特許番号
US05075179

関連ノート

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