Dimethylformamide → HCID 178521103、化合物
反応式
[C-:1]1([C:6]([OH:8])=O)[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:9]1[CH:13]=[CH:12][CH:11]=[CH:10]1.[Fe+2:14].CN(C=O)C.C(Cl)(=O)C([Cl:23])=O>C1(C)C=CC=CC=1>[C-:1]1([C:6]([Cl:23])=[O:8])[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:9]1[CH:13]=[CH:12][CH:11]=[CH:10]1.[Fe+2:14]参加物
5
実験手順
Ferrocene carboxylic acid (5.0 g, 21.7 mmol) was suspended in 40 mL of toluene containing a catalytic amount of DMF; oxalyl chloride (3.08 g, 24 mmol) was added dropwise (approx. addition time 30 min.). The resulting mixture was stirred at room temperature for 3 hours, filtered and the resulting solution used as such in Examples 3,4 and 5.
後処理
- addition(approx. addition time 30 min.)
- filtrationfiltered
出典と根拠
- ORDレコード
- ord-afd3e20770014513a1f81d40f96301b9
- 出典データセット
- uspto-grants-1991_12
- 特許番号
- US05075471
反応ノート
読み込み中…