Hydantoin → HCID 20454111、化合物

HRID 1462201ノート

反応式

HRID 1462201 の反応式
[O:1]1[CH2:6][C:5](=S)[NH:4][C:3](=[O:8])[NH:2]1.[NH:9]1[CH2:15][C:13](=[O:14])[NH:12][C:10]1=[O:11]>O1CCOCC1>[O:8]=[C:3]1[N:4]=[C:5]([N:9]2[CH2:15][C:13](=[O:14])[NH:12][C:10]2=[O:11])[CH2:6][O:1][NH:2]1

参加物

4

反応物 2

HCID 10006HydantoinHCID 30069082H-1,2,4-Oxadiazin-3(4H)-one, dihydro-5-thioxo-

生成物 1

HCID 20454111HCID 20454111、化合物収率 41%

試薬・触媒・溶媒 1

HCID 312751,4-Dioxane溶媒

実験手順

To a solution of 1.0 g (0.0075 mole) of 6H-1,2,4-oxadiazin-3(2H)-one-5(4H)-thione in 50 ml of freshly distilled dry dioxane is added 0.77 g (0.0077 mole) of hydantoin. After stirring at room temperature for 17 hours, the solution is filtered, washed with chloroform and dried to give a yield of 0.6 g (41 percent) of 1-(3,6-dihydro-3-oxo-2H-1,2,4-oxadiazin-5-yl)-2,4-imidazolidinedione.

後処理

  1. filtrationthe solution is filtered
  2. washwashed with chloroform
  3. customdried

出典と根拠

ORDレコード
ord-98a0acb4a4e34e86a6817b12f43a520e
出典データセット
uspto-grants-1984_07
特許番号
US04459403

反応ノート

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