(4-Amino-3-nitrophenyl)acetonitrile → HCID 14891906、化合物
反応式
[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][C:9]#[N:10])=[CH:4][C:3]=1[N+:11]([O-])=O>C(O)C.[Pd]>[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][C:9]#[N:10])=[CH:4][C:3]=1[NH2:11]参加物
4
実験手順
A solution of 1-amino-2-nitro-4-cyanomethylbenzene (6 g.) in ethanol (100 ml.) was hydrogenated for 1.5 hour at atmospheric pressure in presence of 3.6 g. of 10% w/w Pd/C. The catalyst was removed and the solvent was evaporated to give 1,2-diamino-4-cyanomethylbenzene which was used without further purification.
後処理
- customThe catalyst was removed
- customthe solvent was evaporated
出典と根拠
- ORDレコード
- ord-7c81f0484f1f4f928e631eec9aaac12e
- 出典データセット
- uspto-grants-1984_07
- 特許番号
- US04463173
反応ノート
読み込み中…