Benzoyl Peroxide → Methanone, [2-(bromomethyl)phenyl]phenyl-

HRID 1463533

反応式

HRID 1463533 の反応式
[CH3:1][C:2]1[CH:15]=[CH:14][CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5].[Br:16]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:16][CH2:1][C:2]1[CH:15]=[CH:14][CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5]

参加物

5

反応物 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 672302-Methylbenzophenone

生成物 1

HCID 11778133Methanone, [2-(bromomethyl)phenyl]phenyl-

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

A mixture of 2-methylbenzophenone (9.8 g), N-bromosuccinimide (8.9 g), benzoyl peroxide (0.5 g) and carbon tetrachloride (150 ml) was refluxed for 1 hour with light irradiation. The mixture was cooled, and then filtered to remove insoluble substances. The filtrate was concentrated to afford quantitatively the above-titled compound as an oily substance.

後処理

  1. temperaturewas refluxed for 1 hour with light irradiation
  2. temperatureThe mixture was cooled
  3. filtrationfiltered
  4. customto remove insoluble substances
  5. concentrationThe filtrate was concentrated

出典と根拠

ORDレコード
ord-3064d57c8434463a8dcd29dda0dbc922
出典データセット
uspto-grants-1994_04
特許番号
US05300646

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