Water →

HRID 1470562

反応式

[CH2:1]1[S:3][CH:2]1[CH2:4][Cl:5].O.[N:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>C1(C)C=CC=CC=1>[N:7]1[CH:12]=[CH:11][CH:10]=[CH2+:9][CH:8]=1.[Cl-:5].[S:3]1[CH2:2][CH2:4][CH2:1]1

参加物

反応物 3

HCID 962Water

HCID 1049Pyridine

HCID 18588Epithiochlorohydrin

生成物 0

生成物のデータはまだありません。

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度: 50 °C

実験手順

To a solution of epithiochlorohydrin (6.48 g) in toluene (60 mL) were added water (60 mL) and pyridine (23.7 g). The resulting mixture was stirred at 50° C. for 16 h. The two phases were separated and the aqueous phase was then lyophilized to give a yellow oil (13.2 g). The crude oil was filtered over a plug of silica gel, eluting with EtOH:H2O (100:0 to 95:5). The desired salt was obtained as an amber solid was obtained (6.1 g). 1H-NMR (D2O, 500 MHz): 3.59 (t, 2H), 3.91 (t, 2H), 5.99 (dt, 2H), 8.00 (m, 2H), 8.47 (m, 1H), 8.86 (m, 2H). 13C-NMR (D2O, 125 MHz): 32.6 (2C), 63.8, 128.1 (2C), 141.7, 146.5 (2C).

後処理

customThe two phases were separated

出典と根拠

ORDレコード: ord-21e3ade8e94344b4b3667e77d15de88a
出典データセット: uspto-grants-2015_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US09006456B2

反応式

参加物