Tetrahydrofuran → HCID 131731270、化合物

HRID 1475591ノート

反応式

HRID 1475591 の反応式
[I-:1].[La+3:2].[I-].[I-].[C:5]([C:9]1[N-:10][C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])=[C:12]([C:14]([CH3:18])([CH3:17])[CH2:15][CH3:16])[N:13]=1)([CH3:8])([CH3:7])[CH3:6].[K+].[CH2:25]1[CH2:29][O:28][CH2:27][CH2:26]1>>[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[I-:1].[I-:1].[C:5]([C:9]1[N-:13][C:12]([C:14]([CH3:17])([CH3:18])[CH2:15][CH3:16])=[C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])[N:10]=1)([CH3:8])([CH3:7])[CH3:6].[La+3:2]

参加物

4

反応物 3

HCID 8028TetrahydrofuranHCID 25210651LANTHANUM IODIDEHCID 131731268HCID 131731268、化合物

生成物 1

HCID 131731270HCID 131731270、化合物

実験手順

Lanthanum (III) iodide (1.0 g, 0.002 mol) was stirred in 50 mL of THF for 30 mins at room temperature. Potassium 2-tert-butyl-4,5-di-(1,1-dimethylpropyl)imidazolate (0.6 g, 0.002 mol) was added, and the resulting mixture was refluxed for 60 hours. THF was removed by vacuum, followed by hexane extraction, then filtration. The hexane was removed by vacuum, and the resulting solid was crystallized to isolate the final product.

後処理

  1. temperaturethe resulting mixture was refluxed for 60 hours
  2. customTHF was removed by vacuum
  3. extractionfollowed by hexane extraction
  4. filtrationfiltration
  5. customThe hexane was removed by vacuum
  6. customthe resulting solid was crystallized

出典と根拠

ORDレコード
ord-11fdc88107d7442a869453ade4d25830
出典データセット
uspto-grants-2015_04
特許番号
US09018387B2

反応ノート

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