Sodium Hydroxide → 9-Decenoic acid

HRID 1477091

反応式

HRID 1477091 の反応式
C[O:2][C:3](=[O:13])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]=[CH2:12].[OH-].[Na+]>>[C:3]([OH:13])(=[O:2])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]=[CH2:12]

参加物

3

反応物 2

HCID 14798Sodium HydroxideHCID 1778877Methyl 9-decenoate

生成物 1

HCID 617439-Decenoic acid

実験手順

9-decenoic acid methyl ester prepared according to the method set forth in Example 12 is isolated then hydrolyzed under basic conditions (reflux with an excess of dilute aqueous NaOH), followed by removal of methanol. The resulting aqueous solution is then treated with an excess of dilute HCl, and the solution is distilled to provide 9-decenoic acid. Oligomers are then prepared according to the methods set forth in Examples 1 and 2, wherein the oleic acid is replaced with 9-decenoic acid.

後処理

  1. customis isolated
  2. customfollowed by removal of methanol
  3. additionThe resulting aqueous solution is then treated with an excess of dilute HCl
  4. distillationthe solution is distilled

出典と根拠

ORDレコード
ord-d0bda624de1145ab8d61b6a97b8c832d
出典データセット
uspto-grants-2016_08
特許番号
US09403752B2

関連ノート

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