HCID 178444789、化合物 → N,N-dihexyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(trifluoromethoxy)benzamide

HRID 1490842ノート

反応式

HRID 1490842 の反応式
CCCCCCN(CCCCCC)C(=O)c1ccccc1OC(F)(F)F>C1=CCCC=CCC1.C1=CCCC=CCC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.[Ir].[Ir]>CCCCCCN(CCCCCC)C(=O)c1cc(B2OC(C)(C)C(C)(C)O2)ccc1OC(F)(F)F.CCCCCCN(CCCCCC)C(=O)c1ccc(B2OC(C)(C)C(C)(C)O2)cc1OC(F)(F)F

参加物

7

反応物 1

HCID 178444789HCID 178444789、化合物

生成物 2

HCID 91820771N,N-dihexyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(trifluoromethoxy)benzamide収率 20%HCID 140762156N,N-dihexyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(trifluoromethoxy)benzamide収率 79%

試薬・触媒・溶媒 4

HCID 2733548Bis(pinacolato)diborane試薬HCID 42491874,4'-Di-tert-butyl-2,2'-bipyridyl試薬HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium触媒HCID 7809P-Xylene溶媒

反応条件

温度
25 °C

出典と根拠

ORDレコード
ord-71f02c91d402403a8b90142d410c0a65
出典データセット
Borylation dataset from Roche

反応ノート

読み込み中…