Octane, 1-(1,1-dimethylethoxy)- → 4,4,5,5-Tetramethyl-2-[8-[(2-methylpropan-2-yl)oxy]octyl]-1,3,2-dioxaborolane

HRID 1490986

反応式

HRID 1490986 の反応式
CCCCCCCCOC(C)(C)C>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCCCCCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc2ccc3cccnc3c2n1.[Ir].[Ir]>CC(C)(C)OCCCCCCCCB1OC(C)(C)C(C)(C)O1

参加物

6

反応物 1

HCID 11769255Octane, 1-(1,1-dimethylethoxy)-

生成物 1

HCID 1646810104,4,5,5-Tetramethyl-2-[8-[(2-methylpropan-2-yl)oxy]octyl]-1,3,2-dioxaborolane収率 51%

試薬・触媒・溶媒 4

HCID 2733548Bis(pinacolato)diborane試薬HCID 49133562-Methyl-1,10-phenanthroline試薬HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium触媒HCID 9266Cyclooctane溶媒

反応条件

温度
100 °C

出典と根拠

ORDレコード
ord-8b9505cf99af4f71aa86648a7e9c245a
出典データセット
Borylation dataset from Roche

関連ノート

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